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Short communicationSynthesis of novel ferrocene-based conjugated microporous polymers with intrinsic magnetism

Gen Li - No affiliation found

2017/08/01 Short communication DOI: 10.1016/j.eurpolymj.2017.06.034 Journal: European Polymer Journal

Abstract:

AbstractThe combination of conjugated microporous polymers (CMPs) with magnetic property was a meaningful issue in theoretical and practical study. Endowing CMPs with magnetic property can extend its application to the fields like magnetic sensor and magnetic separation. Ferrocene-based conjugated microporous polymers (Fc-CMPs) with intrinsic magnetism were constructed with ferrocene derivative as a building unit by Pd-mediated Sonogashira-Hagihara cross-coupling reaction. Fc-CMPs exhibited excellent porosity, and the BET surface area of Fc-CMPs was up to 520 m2/g. The results indicated that the saturation magnetization of Fc-CMPs could be tuned by combining ferrocene derivative with monomers with different π-conjugated degree.