Identification and separation of spectral change due to temperature increase in nanosecond transient absorption spectra of polydiacetylene thin films
Review articleOpen access

AbstractTime dependence of a photoinduced absorbance change in a thin film of polydiacetylene PDA-3BCMU (poly-4,6-decadiyne-1, 10-diol-bis(n-butoxycarbonyl-methylurethane)) was separated from the effect of increasing sample temperature by a newly designed method. The resultant nonthermal contribution relaxes via a geminate recombination process, probably due to polarons.

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