Preliminary communicationHydrostannation and hydrostannolysis by diorganotin hydrides R2SnXH (X = halide, carboxylate, sulphonate, etc.)
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AbstractDiorganotin halide hydrides or carboxylate hydrides, R2SnXH, will bring about the hydrostannolysis of alkyl halides, or the hydrostannation of alkynes or of carbonyl compounds at or below room temperature. The reactions show different chemo-, regio-, and stereo-selectivities from those involving tributyltin hydride.

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