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Outer-sphere addition compounds of MoO2Br2(H2O)2 with ethers. Molecular structure of MoO2Br2(H2O)2·L (L=2,5,8-trioxanonane; 2,5,8,11,14-pentaoxapentadecane)

Francisco J Arnáiz - No affiliation found

2001/10/15 Full-length article DOI: 10.1016/S0277-5387(01)00852-X Journal: Polyhedron

Abstract:

AbstractOuter-sphere addition compounds of MoO2Br2(H2O)2 with diethyl ether, dioxane, glyme, diglyme, triglyme and tetraglyme have been readily prepared by crystallizing diethyl ether extracts of a solution of sodium molybdate in concentrated hydrobromic acid in the presence of the corresponding ether. The molecular structures of MoO2Br2(H2O)2·L (L=2,5,8-trioxanonane; 2,5,8,11,14-pentaoxapentadecane) have been established by X-ray diffraction analysis.