Reactions of fullerenols C60(OH)x (x=12, 18) with trialkoxysilanes (RO)3Si(CH2)3X (R=Me, X=Cl; R=Et, X=NH2)
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Abstract:

AbstractTransesterification reactions of trialkoxysilanes SiR(OR′)3 [R=(CH2)3Cl, R′=Me; R=(CH2)3NH2, R′=Et] with fullerenols C60(OH)x (x=12, 18) give different products containing totally or partially hydrolyzed OSiR(OR′)2, O2SiR(OR′) and, possibly, O3SiR attached species in a variable number. The yields with respect to the fullerenols are very high.

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