Preliminary communicationA cationic ylide complex of platinum(ii): its structure and formation from a chloromethyl-platinum complex
Review articleOpen access
1982/07/06 Short communication DOI: 10.1016/S0022-328X(00)89220-7
Journal: Journal of Organometallic Chemistry
AbstractThe reactions of cis-or trans-[Pt(PPh3)2(CH2CL)I] with triphenylphosphine give the ylide complex cis-[Pt(PPh3)2(CH2PPh3)Cl]I. The reactions involve a novel migration of Cl from a CH2 group to Pt. The structure of the cationic ylide complex has been determined by X-ray crystallography.
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