Preliminary communicationA cationic ylide complex of platinum(ii): its structure and formation from a chloromethyl-platinum complex
Review articleOpen access
Abstract:

AbstractThe reactions of cis-or trans-[Pt(PPh3)2(CH2CL)I] with triphenylphosphine give the ylide complex cis-[Pt(PPh3)2(CH2PPh3)Cl]I. The reactions involve a novel migration of Cl from a CH2 group to Pt. The structure of the cationic ylide complex has been determined by X-ray crystallography.

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