Catalytic addition of trihalogenomethanesulfenyl chlorides to olefinic compounds
Review articleOpen access

AbstractTrifluoroacetic acid has been found to be an efficient catalyst for the addition of fluorochloromethanesulfenyl chlorides CFnCl3−nSCl (n = 1, 2, 3) to olefins such as cyclohexene, 1-hexene, allyl bromide and vinyl bromide. The reaction with cyclohexene led to trans adducts. The addition to asymmetrical olefins afforded a mixture of Markovnikov- and anti-Markovnikov oriented adducts. The factors influencing the reaction course are discussed.

Request full text

References (0)

Cited By (0)

No reference data.
No citation data.
Join Copernicus Academic and get access to over 12 million papers authored by 7+ million academics.
Join for free!